Yb3+:CaF2 are among most studied and promising crystals for the development of short-pulse, high-energy, high-power diode-pumped solid-state lasers. There are several reasons that explain this trend. Firstly, calcium fluoride is a simple cubic crystal whose crystallographic properties are fairly well known.
Moreover, this crystal can be grown of large dimension and optical quality. The simple structure of this crystal contributes to its good thermal properties. Finally, Yb-doped calcium fluorides feature very broad and smooth emission bands, which is exceptional for cubic crystals.
Spectroscopic and thermo-mechanical properties
Yb:CaF2 crystals